Transition metal-catalyzed carbon-carbon bond formation with grignard reagents - Novel reactions with a classic reagent

被引:2
|
作者
Shinokubo, H [1 ]
Oshima, K
机构
[1] Kyoto Univ, Dept Chem, Grad Sch Sci, Kyoto 6068502, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan
关键词
chromium; cobalt; Grignard reagent; iron; manganese;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Organomagnesium compounds are among the most useful organometallic reagents in organic synthesis. Besides their classical nucleophilic reactions to carbonyl compounds, Grignard reagents gain versatile reactivity when combined with various transition metal salts. In this article, we review mainly our own studies on manganese-, iron-, chromium-, and cobalt-catalyzed carbon-carbon bond formation reactions using Grignard reagents. Other closely related research in this field is also discussed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码:2081 / 2091
页数:11
相关论文
共 50 条
  • [41] Transition-Metal-Catalyzed Carbon-Carbon Bond Activation in Asymmetric Synthesis
    Bi, Xiufen
    Zhang, Qiuchi
    Gu, Zhenhua
    CHINESE JOURNAL OF CHEMISTRY, 2021, 39 (05) : 1397 - 1412
  • [42] Transition metal-catalyzed organic reactions in supercritical carbon dioxide
    Jiang, HF
    CURRENT ORGANIC CHEMISTRY, 2005, 9 (03) : 289 - 297
  • [43] Enantioselective Transition-Metal Catalyzed Carbon–Carbon Bond Formation Reactions using Novel Chiral Ferrocenes and Cyclophanes
    Xue Long Hou
    Shu Li You
    Tao Tu
    Wei Ping Deng
    Xun Wei Wu
    Ming Li
    Ke Yuan
    Tang Zhi Zhang
    Li Xin Dai
    Topics in Catalysis, 2005, 35 : 87 - 103
  • [44] Developments in transition metal-catalyzed reactions in Supercritical carbon dioxide
    Song, RQ
    Zeng, JQ
    Zhong, B
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2002, 22 (04) : 248 - 253
  • [45] Transition-Metal-Catalyzed Laboratory-Scale Carbon-Carbon Bond-Forming Reactions of Ethylene
    Saini, Vaneet
    Stokes, Benjamin J.
    Sigman, Matthew S.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (43) : 11206 - 11220
  • [46] Carbon-Carbon Bond Forming Reactions in Diazines via Transition-Metal-Catalyzed C-H Bond Activation
    Gramage-Doria, Rafael
    Bruneau, Christian
    SYNTHESIS-STUTTGART, 2023, 55 (21): : 3470 - 3486
  • [47] Beckmann Fragmentation and Successive Carbon-Carbon Bond Formation Using Grignard Reagents via Phosphonium Salt Intermediates
    Fujioka, Hiromichi
    Matsumoto, Nao
    Kuboki, Yuichi
    Mitsukane, Hidenobu
    Ohta, Reiya
    Kimura, Takashi
    Murai, Kenichi
    CHEMICAL & PHARMACEUTICAL BULLETIN, 2016, 64 (07) : 718 - 722
  • [48] Carbon-Carbon Bond Formation of Trifluoroacetyl Amides with Grignard Reagents via C(O)-CF3 Bond Cleavage
    Zhu, Longzhi
    Le, Liyuan
    Yang, Mingpan
    Au, Chak-Tong
    Qiu, Renhua
    Kambe, Nobuaki
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (09): : 5635 - 5644
  • [49] ORGANOCHROMIUM REAGENTS FOR HIGHLY SELECTIVE CARBON-CARBON BOND FORMATION
    TAKAI, K
    UTIMOTO, K
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1988, 46 (01) : 66 - 77
  • [50] NI(II)PHOSPHINE AND CO(II)-PHOSPHINE COMPLEX CATALYZED CARBON-CARBON BOND FORMATION BETWEEN ORGANIC TELLURIDES AND GRIGNARD-REAGENTS
    UEMURA, S
    FUKUZAWA, S
    TETRAHEDRON LETTERS, 1982, 23 (11) : 1181 - 1184