Transition metal-catalyzed carbon-carbon bond formation with grignard reagents - Novel reactions with a classic reagent

被引:2
|
作者
Shinokubo, H [1 ]
Oshima, K
机构
[1] Kyoto Univ, Dept Chem, Grad Sch Sci, Kyoto 6068502, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan
关键词
chromium; cobalt; Grignard reagent; iron; manganese;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Organomagnesium compounds are among the most useful organometallic reagents in organic synthesis. Besides their classical nucleophilic reactions to carbonyl compounds, Grignard reagents gain versatile reactivity when combined with various transition metal salts. In this article, we review mainly our own studies on manganese-, iron-, chromium-, and cobalt-catalyzed carbon-carbon bond formation reactions using Grignard reagents. Other closely related research in this field is also discussed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码:2081 / 2091
页数:11
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