Photoinduced radical-initiated carboxylative cyclization of allyl amines with carbon dioxide

被引：94
|
作者：
Wang, Mei-Yan [1 ,2 ]
Cao, Yu [1 ,2 ]
Liu, Xi [1 ,2 ]
Wang, Ning [1 ,2 ]
He, Liang-Nian [1 ,2 ,3 ]
Li, Si-Han [1 ,2 ]
机构：
[1] Nankai Univ, State Key Lab, Tianjin, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin, Peoples R China
[3] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn, 94 Weijin Rd, Tianjin 300071, Peoples R China
来源：
GREEN CHEMISTRY | 2017年 / 19卷 / 05期
基金：
中国国家自然科学基金;
关键词：
C-H BONDS; VISIBLE-LIGHT; CO2; REDUCTION; PHOTOCATALYTIC REDUCTION; PHOTOREDOX CATALYSIS; IONIC LIQUIDS; TRIFLUOROMETHYLATION; EFFICIENT; TIO2; 2-OXAZOLIDINONES;
D O I：
10.1039/c6gc03200a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Visible light-promoted CO2 upgrading: a highly efficient and metal-free photochemical method for the carboxylative cyclization of allyl amines with CO2 is reported to prepare perfluoroalkylated oxazolidinones with high efficiency under ambient conditions by using perfluoroalkyl iodides as radical sources.
引用
收藏
页码：1240 / 1244
页数：5
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