Photoinduced radical-initiated carboxylative cyclization of allyl amines with carbon dioxide

被引：94
|
作者：
Wang, Mei-Yan [1 ,2 ]
Cao, Yu [1 ,2 ]
Liu, Xi [1 ,2 ]
Wang, Ning [1 ,2 ]
He, Liang-Nian [1 ,2 ,3 ]
Li, Si-Han [1 ,2 ]
机构：
[1] Nankai Univ, State Key Lab, Tianjin, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin, Peoples R China
[3] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn, 94 Weijin Rd, Tianjin 300071, Peoples R China
来源：
GREEN CHEMISTRY | 2017年 / 19卷 / 05期
基金：
中国国家自然科学基金;
关键词：
C-H BONDS; VISIBLE-LIGHT; CO2; REDUCTION; PHOTOCATALYTIC REDUCTION; PHOTOREDOX CATALYSIS; IONIC LIQUIDS; TRIFLUOROMETHYLATION; EFFICIENT; TIO2; 2-OXAZOLIDINONES;
D O I：
10.1039/c6gc03200a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Visible light-promoted CO2 upgrading: a highly efficient and metal-free photochemical method for the carboxylative cyclization of allyl amines with CO2 is reported to prepare perfluoroalkylated oxazolidinones with high efficiency under ambient conditions by using perfluoroalkyl iodides as radical sources.
引用
收藏
页码：1240 / 1244
页数：5
相关论文
共 50 条
  • [31] Stereoselective formation of α-alkylidene cyclic carbonates via carboxylative cyclization of propargyl alcohols in supercritical carbon dioxide
    Kayaki, Yoshihito
    Yamamoto, Masafumi
    Ikariya, Takao
    JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (02): : 647 - 649
  • [32] Robust Silver(I) Catalyst for the Carboxylative Cyclization of Propargylic Alcohols with Carbon Dioxide under Ambient Conditions
    Song, Qing-Wen
    He, Liang-Nian
    ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (08) : 1251 - 1258
  • [33] A Carboxylative Cyclization of Propargylic Amines with Carbon Dioxide Catalyzed by the N-Heterocyclic Carbene 1,3-Di-tert-butylimidazol-2-ylidene (ItBu)
    Fujita, Ken-ichi
    Sato, Junichi
    Fujii, Akira
    Onozawa, Shun-ya
    Yasuda, Hiroyuki
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 5 (06) : 828 - 833
  • [34] Highly Functional Allyl-Bicyclo[1.1.1]pentane Synthesis by Radical-Initiated Three-Component Stereoselective Allylation
    Zeng, Qian
    Shi, Wangyu
    Kleij, Arjan W.
    JACS AU, 2025, 5 (02): : 913 - 921
  • [35] Unusual structure of a C-arylated gibberellin bis-γ-lactone formed from a free radical-initiated cyclization
    Mander, Lewis N.
    Sherburn, Michael S.
    Willis, Anthony C.
    1997, (53)
  • [36] Metal-free sulfonyl radical-initiated cascade cyclization to access sulfonated indolo[1,2-a]quinolines
    Sun, Kai
    Chen, Xiao-Lan
    Zhang, Yin-Li
    Li, Kai
    Huang, Xian-Qiang
    Peng, Yu-Yu
    Qu, Ling-Bo
    Yu, Bing
    CHEMICAL COMMUNICATIONS, 2019, 55 (84) : 12615 - 12618
  • [37] Organometallic radical-initiated carbon-sulfur bond cleavage and carbon-carbon coupling in dithiocarbamate and thiocarbenoid cyclopentadienylchromium complexes
    Goh, LY
    Weng, ZQ
    Hor, ATS
    Leong, WK
    ORGANOMETALLICS, 2002, 21 (21) : 4408 - 4414
  • [38] The unusual structure of a C-arylated gibberellin bis-gamma-lactone formed from a free radical-initiated cyclization
    Mander, LN
    Sherburn, MS
    Willis, AC
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 223 - 225
  • [39] Metal-free polychloromethyl radical-initiated cyclization of unactivated N-allylindoles towards pyrrolo[1,2-a]indoles
    Shan, Yujia
    Yang, Zixian
    Yu, Jin-Tao
    Pan, Changduo
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (26) : 5259 - 5263
  • [40] Highly Selective Carboxylative Cyclization of Allenylmethylamines with Carbon Dioxide Using N-Heterocyclic Carbene-Silver(I) Catalysts
    Yamashita, Kyohei
    Hase, Shun
    Kayaki, Yoshihito
    Ikariya, Takao
    ORGANIC LETTERS, 2015, 17 (10) : 2334 - 2337
12345