Iridium-catalyzed reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes

被引：97
|
作者：
Yasukawa, T [1 ]
Satoh, T [1 ]
Miura, M [1 ]
Nomura, M [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 43期
关键词：
D O I：
10.1021/ja0280269
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Benzoyl chlorides efficiently react with 2 equiv of dialkylacetylenes as well as diphenylacetylene in the presence of an iridium catalyst accompanied by decarbonylation to produce 1,2,3,4-tetrasubstituted naphthalenes in good yields. Use of 2-naphthoyl chlorides selectively affords the corresponding anthracene derivatives. Copyright © 2002 American Chemical Society.
引用
收藏
页码：12680 / 12681
页数：2
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