Iridium-catalyzed reaction of aroyl chlorides with internal alkynes to produce substituted naphthalenes and anthracenes

被引：97

作者：

Yasukawa, T ^{[1
]}

Satoh, T ^{[1
]}

Miura, M ^{[1
]}

Nomura, M ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 43期

关键词：

D O I：

10.1021/ja0280269

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzoyl chlorides efficiently react with 2 equiv of dialkylacetylenes as well as diphenylacetylene in the presence of an iridium catalyst accompanied by decarbonylation to produce 1,2,3,4-tetrasubstituted naphthalenes in good yields. Use of 2-naphthoyl chlorides selectively affords the corresponding anthracene derivatives. Copyright © 2002 American Chemical Society.

引用

页码：12680 / 12681

页数：2

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