Synthesis and crystal structure of the tetranuclear copper(I) complex [Cu4I4(MPTQ)(2)] with a N,S,N'-tridentate ligand (MPTQ=8-((2-pyridylmethyl)thio)quinoline)

被引：24
|
作者：
Su, CY [1 ]
Kang, BS [1 ]
Sun, J [1 ]
机构：
[1] CHINESE ACAD SCI, SHANGHAI INST ORGAN CHEM, ORGANOMET CHEM LAB, SHANGHAI 200032, PEOPLES R CHINA
来源：
CHEMISTRY LETTERS | 1997年 / 08期
关键词：
D O I：
10.1246/cl.1997.821
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copper(I) iodide reacts with 8-((2-pyridylmethyl)thio) quinoline (MPTQ) to give the tetranuclear cluster complex [Cu4I4(MPTQ)(2)] which has been structurally characterized, showing that the Cu4I4 core exists in a distorted chair-like structure with four copper atoms forming parallelogram which is bridged by iodine atoms on each short sides, by S, N-MPTQ on each long sides and with two additional iodine atoms face-bridging sets of three copper atoms on opposite sides of the parallelogram.
引用
收藏
页码：821 / 822
页数：2
相关论文
共 50 条
  • [1] Copper(I) Complex [Cu(ca2dapte)(NCS)] with the Flexible N2S2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure
    Morshedi, Mahbod
    Amirnasr, Mehdi
    Triki, Smail
    Khalaji, Aliakbar Dehno
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (01) : 39 - 43
  • [2] Copper(I) Complex [Cu(ca2dapte)(NCS)] with the Flexible N2S2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure
    Mahbod Morshedi
    Mehdi Amirnasr
    Smail Triki
    Aliakbar Dehno Khalaji
    Journal of Chemical Crystallography, 2011, 41 : 39 - 43
  • [3] Synthesis and Crystal Structure of a Dinuclear Cu(II) Complex with N,N,N′,N′-Tetrakis(2-pyridylmethyl)-1,4-xylenediamine
    Sugiyama, Junya
    Yoneda, Ko
    Yamada, Yasunori
    Koikawa, Masayuki
    X-RAY STRUCTURE ANALYSIS ONLINE, 2022, 38 : 19 - 20
  • [4] Crystal structure of tetra-μ3-iodo-tetrakis[(nicotine)copper(I)], Cu4I4(C10H14N2)4
    Jiang, Zheng-Jing
    Zhang, Yu
    Tang, Guo-Dong
    Zhao, Jian-Ying
    Lu, Lu-De
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2009, 224 (03): : 466 - 468
  • [5] SYNTHESIS AND STRUCTURE OF (N,N,N',N'-TETRAKIS(2-PYRIDYLMETHYL)ETHYLENEDIAMINE)DICOPPER(I) AND ITS DICARBONYL ADDUCT
    GAGNE, RR
    KREH, RP
    DODGE, JA
    MARSH, RE
    MCCOOL, M
    INORGANIC CHEMISTRY, 1982, 21 (01) : 254 - 261
  • [6] Synthesis, characterization, and crystal structure of the copper(II) complex of the optical active polypyridylmethylamine ligand:: N,N,N′-tris(2-pyridylmethyl)-S-2-(aminomethyl) piperidine = S-P3pipda
    Kurosaki, H
    Koike, H
    Mori, S
    Ogata, Y
    Yamaguchi, Y
    Goto, M
    INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (11) : 1229 - 1232
  • [7] Synthesis, crystal structure, spectroscopy, and nuclease activity of copper(II) complexes containing N,N-bis(2-pyridylmethyl)amine ligand
    Qian, Jing
    Wang, Li-Ping
    Tian, Jin-Lei
    Yan, Shi-Ping
    JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (11) : 1991 - 2001
  • [8] CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMERIC COPPER(I) IODIDE-PIPERIDINE, A COMPLEX WITH A TETRAHEDRAL CU4I4 CORE
    SCHRAMM, V
    INORGANIC CHEMISTRY, 1978, 17 (03) : 714 - 718
  • [9] FLUORESCENT COPPER(I) COMPLEXES - CORRELATION OF STRUCTURAL AND EMISSION CHARACTERISTICS OF [(CUL(QUIN)2)2] AND [CU4I4(QUIN)4] (QUIN = QUINOLINE)
    RATH, NP
    HOLT, EM
    TANIMURA, K
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (11): : 2303 - 2310
  • [10] Mononuclear manganese(III) complex with a monodeprotonated N-(2-pyridylmethyl)iminodiisopropanol ligand: synthesis, crystal structure, and catalytic properties
    Choi, Jihye
    Lee, Sojeong
    Jeong, Ah Rim
    Kim, Cheal
    Min, Kil Sik
    INORGANICA CHIMICA ACTA, 2019, 498
12345