Copper(I) Complex [Cu(ca2dapte)(NCS)] with the Flexible N2S2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure

被引：8
|
作者：
Morshedi, Mahbod [1 ]
Amirnasr, Mehdi [1 ]
Triki, Smail [2 ]
Khalaji, Aliakbar Dehno [3 ]
机构：
[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran
[2] Univ Bretagne Occidentale, CNRS, UMR 6521, F-29285 Brest, France
[3] Gorgan Univ Agr Sci & Nat Resources, Dept Sci, Gorgan 4918943464, Iran
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期
关键词：
N2S2; Schiff-base; Tridentate coordination mode; Copper (I) complex; X-ray crystal structure; SILVER(I) COORDINATION ARCHITECTURES; PYRIDYL DITHIOETHER LIGANDS; MONONUCLEAR COMPLEXES; HETEROCYCLIC THIOETHERS; CHEMISTRY; CHROMOPHORE; POLYMER; CAGE; BR;
D O I：
10.1007/s10870-010-9833-4
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
New copper(I) complex involving the flexible N2S2 Schiff-base ligand ca(2)dapte [Cu(ca(2)dapte)(NCS)], [ca(2)dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio)ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca(2)dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to the metal ion through its nitrogen atom. Crystal data: space group P-1, a = 10.7486(7), b = 12.3737(13), c = 12.7578(11) , alpha = 89.385(7), beta = 68.527(7), gamma = 66.190(8)A degrees; V = 1425.8(2) (3), Z = 2, R = 0.0417, wR (2) = 0.0744.
引用
收藏
页码：39 / 43
页数：5
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