Copper(I) Complex [Cu(ca2dapte)(NCS)] with the Flexible N2S2 Schiff-base Tridentate Ligand: Synthesis, Characterization and Crystal Structure

被引：8

作者：

Morshedi, Mahbod ^{[1
]}

Amirnasr, Mehdi ^{[1
]}

Triki, Smail ^{[2
]}

Khalaji, Aliakbar Dehno ^{[3
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran

[2] Univ Bretagne Occidentale, CNRS, UMR 6521, F-29285 Brest, France

[3] Gorgan Univ Agr Sci & Nat Resources, Dept Sci, Gorgan 4918943464, Iran

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2011年 / 41卷 / 01期

关键词：

N2S2; Schiff-base; Tridentate coordination mode; Copper (I) complex; X-ray crystal structure; SILVER(I) COORDINATION ARCHITECTURES; PYRIDYL DITHIOETHER LIGANDS; MONONUCLEAR COMPLEXES; HETEROCYCLIC THIOETHERS; CHEMISTRY; CHROMOPHORE; POLYMER; CAGE; BR;

D O I：

10.1007/s10870-010-9833-4

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

New copper(I) complex involving the flexible N2S2 Schiff-base ligand ca(2)dapte [Cu(ca(2)dapte)(NCS)], [ca(2)dapte = N,N'-bis-(cinnamaldehyde)-1,2-di(o-iminophenylthio)ethane], has been synthesized and structurally characterized by X-ray diffraction analysis. The coordination polyhedron around the Cu(I) center is best described as a distorted tetrahedron. The flexible N2S2 Schiff-base ligand ca(2)dapte acts as a tridentate ligand via two S atoms and one N atom, while the NCS- ligand is coordinated to the metal ion through its nitrogen atom. Crystal data: space group P-1, a = 10.7486(7), b = 12.3737(13), c = 12.7578(11) , alpha = 89.385(7), beta = 68.527(7), gamma = 66.190(8)A degrees; V = 1425.8(2) (3), Z = 2, R = 0.0417, wR (2) = 0.0744.

引用

页码：39 / 43

页数：5

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