Synthesis and crystal structure of the tetranuclear copper(I) complex [Cu4I4(MPTQ)(2)] with a N,S,N'-tridentate ligand (MPTQ=8-((2-pyridylmethyl)thio)quinoline)

被引：24

作者：

Su, CY ^{[1
]}

Kang, BS ^{[1
]}

Sun, J ^{[1
]}

机构：

[1] CHINESE ACAD SCI, SHANGHAI INST ORGAN CHEM, ORGANOMET CHEM LAB, SHANGHAI 200032, PEOPLES R CHINA

来源：

CHEMISTRY LETTERS | 1997年 / 08期

关键词：

D O I：

10.1246/cl.1997.821

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(I) iodide reacts with 8-((2-pyridylmethyl)thio) quinoline (MPTQ) to give the tetranuclear cluster complex [Cu4I4(MPTQ)(2)] which has been structurally characterized, showing that the Cu4I4 core exists in a distorted chair-like structure with four copper atoms forming parallelogram which is bridged by iodine atoms on each short sides, by S, N-MPTQ on each long sides and with two additional iodine atoms face-bridging sets of three copper atoms on opposite sides of the parallelogram.

引用

页码：821 / 822

页数：2

共 50 条

[21] Synthesis and crystal structure of N,N'-dimethyldithioarbamato-copper(I) polymer {[Cu(Me2dtc)]2}n
Zhang, W
Zhu, XL
Cheng, ZP
Zhu, J
Lang, JP
Lu, JM
CHINESE JOURNAL OF CHEMISTRY, 2004, 22 (08) : 888 - 890
[22] Synthesis and structure of tetranuclear μ4-S copper(I) complex with bis(diphenylphosphino)methane
Yang, RN
Sun, YA
Hu, XY
Jin, DM
ACTA CHIMICA SINICA, 2000, 58 (06) : 727 - 730
[23] Synthesis, Crystal Structure and Protein Tyrosine Phosphatase Inhibition of a Copper(II) Complex with N-(2-Pyridylmethyl)-L-serine
Li Yanhong
Yuan Caixia
Lu Liping
Zhu Miaoli
Fu Xueqi
Xing Shu
Gao Zengqiang
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2016, 37 (12): : 2138 - 2143
[24] Synthesis and crystal structure of [Cu2I2(tptz)]n
Yao Xiao-Qiang
Yan Pen-Ji
Song Yu-Min
Li Yi-Zhi
Zheng He-Gen
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (07) : 1148 - 1151
[25] SYNTHESIS AND PROPERTIES OF TETRANUCLEAR OCTAHALO COPPER(II) COMPLEXES, N4CU4X8 (N = N, N-DIETHYLNICOTINAMIDE, X = CL, BR OR I), AND TRANSMETALATION OF N4CU4CL8 WITH NI(NS)2, (NS = S-METHYL ISOPROPYLIDENEHYDRAZINECARBOTHIOATE) IN APROTIC MEDIA
ELSAYED, MA
POLYHEDRON, 1992, 11 (10) : 1261 - 1267
[26] Paramagnetic resonance and magnetism of copper(II) complexes with N,N',N'',N'''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane
Voronkova, VK
Vuckovic, G
Jezierska, J
Mrozinski, J
Yablokov, YV
INORGANICA CHIMICA ACTA, 1997, 262 (02) : 147 - 155
[27] Copper(I) nitrate complexes.: Synthesis and crystal structure of [Cu2(μ-DATU)2(DATU)4](NO3)2 (DATU=N,N′-diallylthiourea)
Filinchuk, YE
Oliinik, VV
Schollmeier, D
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1999, 25 (03) : 209 - 213
[28] Crystal structure of dinuclear copper(I) complex with 1,2,4,5-tetramethylmercaptobenzene, [Cu(tmmb)I](2)
Suenaga, Y
Maekawa, M
KurodaSowa, T
Munakata, M
Morimoto, H
Hiyama, N
Kitagawa, S
ANALYTICAL SCIENCES, 1997, 13 (04) : 651 - 652
[29] Crystal structure of tetrakis(4,4′-bipyridine)copper(I) perchlorate, [Cu(C10H8N2)4] [ClO4]
Qin, Jian-Hua
Li, Xiao-Ling
Guo, Hui
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (03): : 318 - 320
[30] A new mixed-ligand complex of copper(II) containing N-(2-pyridylmethyl)-2-pyrazinecarboxamide (NPyPzCa): Synthesis, molecular and crystal structure and properties of [Cu(NPyPzCa)(NO3)(DMSO)]
Khavasi, Hamid Reza
Sasan, Koroush
Hashjin, Shahin Sowlati
Zahedi, Mansour
COMPTES RENDUS CHIMIE, 2011, 14 (06) : 563 - 567

← 1 2 3 4 5 →