Palladium(0) supported on carbon nanotubes as an efficient catalyst of the CC bond hydrogenation

被引:32
|
作者
Starodubtseva, Eugenia V. [1 ]
Vinogradov, Maxim G. [1 ]
Turova, Olga V. [1 ]
Bumagin, Nikolai A. [2 ]
Rakov, Eduard G. [3 ]
Sokolov, Viatcheslav I. [4 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[3] DI Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia
[4] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
关键词
Palladium; Carbon nanotubes; Catalytic hydrogenation; Acetylenic hydrocarbons; SELECTIVE HYDROGENATION; NANOPARTICLES; PD;
D O I
10.1016/j.catcom.2009.03.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Palladium supported on carbon nanotubes catalyzes efficiently hydrogenation of the C C bond of tolane, phenylacetylene and 1-heptyne to give a mixture of intermediate ethylenic and completely reduced hydrocarbons. The composition of hydrogenation products depends greatly on the structure of the starting reagent and reaction conditions. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1441 / 1442
页数:2
相关论文
共 50 条
  • [41] Hydrogenation of Ethyl p-Nitrobenzoate on Carbon-Supported Palladium-Triphenylphosphine Catalyst
    I. I. Obraztsova
    O. A. Efimov
    Russian Journal of Applied Chemistry, 2004, 77 : 511 - 512
  • [42] The application of neutron imaging to examine ethene hydrogenation over a carbon-supported palladium catalyst
    Cavaye, Hamish
    E. Ballas, Christos
    Kockelmann, Winfried
    Parker, Stewart F.
    Collier, Paul
    York, Andrew P. E.
    Lennon, David
    SCIENTIFIC REPORTS, 2025, 15 (01):
  • [43] Hydrogenation of ethyl p-nitrobenzoate on carbon-supported palladium-triphenylphosphine catalyst
    Obraztsova, I.I.
    Efimov, O.A.
    Russian Journal of Applied Chemistry, 2004, 77 (03): : 511 - 512
  • [44] Propyne hydrogenation: characteristics of a carbon-supported palladium catalyst that exhibits a kinetic discontinuity effect
    Marshall, R
    Webb, G
    Jackson, SD
    Lennon, D
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 226 (02) : 227 - 230
  • [45] Hydrogenation of ethyl p-nitrobenzoate on carbon-supported palladium-triphenylphosphine catalyst
    Obraztsova, II
    Efimov, OA
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2004, 77 (03) : 511 - 512
  • [46] Strontium as an efficient promoter for supported palladium hydrogenation catalysts
    Pillai, UR
    Sahle-Demessie, E
    APPLIED CATALYSIS A-GENERAL, 2005, 281 (1-2) : 31 - 38
  • [47] Reaction kinetics of nitrobenzene hydrogenation on a palladium catalyst supported on nanodiamonds
    Obraztsova, I. I.
    Eremenko, N. K.
    Velyakina, Yu. N.
    KINETICS AND CATALYSIS, 2008, 49 (03) : 401 - 406
  • [48] Reaction kinetics of nitrobenzene hydrogenation on a palladium catalyst supported on nanodiamonds
    I. I. Obraztsova
    N. K. Eremenko
    Yu. N. Velyakina
    Kinetics and Catalysis, 2008, 49 : 401 - 406
  • [49] Catalytic activity of maghemite supported palladium catalyst in nitrobenzene hydrogenation
    Hajdu, Viktoria
    Prekob, Adam
    Muranszky, Gabor
    Kocserha, Istvan
    Konya, Zoltan
    Fiser, Bela
    Viskolcz, Bela
    Vanyorek, Laszlo
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2020, 129 (01) : 107 - 116
  • [50] Pt catalyst supported on carbon nanotubes for selective hydrogenation of citral and differential heats of CO adsorption
    Zhang, YJ
    Li, JY
    Li, WZ
    Xin, Q
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2005, 26 (07): : 1345 - 1347