Palladium(0) supported on carbon nanotubes as an efficient catalyst of the CC bond hydrogenation

被引:32
|
作者
Starodubtseva, Eugenia V. [1 ]
Vinogradov, Maxim G. [1 ]
Turova, Olga V. [1 ]
Bumagin, Nikolai A. [2 ]
Rakov, Eduard G. [3 ]
Sokolov, Viatcheslav I. [4 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[3] DI Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia
[4] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
关键词
Palladium; Carbon nanotubes; Catalytic hydrogenation; Acetylenic hydrocarbons; SELECTIVE HYDROGENATION; NANOPARTICLES; PD;
D O I
10.1016/j.catcom.2009.03.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Palladium supported on carbon nanotubes catalyzes efficiently hydrogenation of the C C bond of tolane, phenylacetylene and 1-heptyne to give a mixture of intermediate ethylenic and completely reduced hydrocarbons. The composition of hydrogenation products depends greatly on the structure of the starting reagent and reaction conditions. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1441 / 1442
页数:2
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