Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes

被引：21

作者：

Tetard, D ^{[1
]}

Verlhac, JB ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,URA 35 CNRS,F-33405 TALENCE,FRANCE

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 113卷 / 1-2期

关键词：

alkane hydroxylation; manganese complex; iron complex; hydroperoxyde; peracid;

D O I：

10.1016/S1381-1169(97)80001-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylation reactions. Moreover, it was demonstrated that the cleavage of the peroxy bond occurred mainly by homolysis.

引用

页码：223 / 230

页数：8

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