Alkane hydroxylation reactions catalysed by binuclear manganese and iron complexes

被引：21
|
作者：
Tetard, D [1 ]
Verlhac, JB [1 ]
机构：
[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,URA 35 CNRS,F-33405 TALENCE,FRANCE
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 113卷 / 1-2期
关键词：
alkane hydroxylation; manganese complex; iron complex; hydroperoxyde; peracid;
D O I：
10.1016/S1381-1169(97)80001-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylation reactions. Moreover, it was demonstrated that the cleavage of the peroxy bond occurred mainly by homolysis.
引用
收藏
页码：223 / 230
页数：8
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