Controlled Assembly of Inorganic-Organic Frameworks Based on [SeMo6O21]4- Polyanion

被引：38
|
作者：
Yang, Donghui [1 ]
Li, Suzhi [2 ]
Ma, Pengtao [1 ]
Wang, Jingping [1 ]
Niu, Jingyang [1 ]
机构：
[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Henan Key Lab Polyoxometalate, Kaifeng 475004, Henan, Peoples R China
[2] Shangqiu Normal Univ, Engn Res Ctr Funct Mat Preparat, Coll Chem & Chem Engn, Shangqiu 476000, Henan, Peoples R China
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 24期
基金：
中国国家自然科学基金;
关键词：
STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; POLYOXOMETALATE; FUNCTIONALIZATION; COMPLEXES; HETEROPOLYMOLYBDATES; OCTAMOLYBDATES; MOLYBDENUM(V); DERIVATIVES;
D O I：
10.1021/ic401804e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chemical system based on [SeMo6O21](4-) polyanion and carboxylate ligand has been investigated. According to the inherent nature of organic groups, a series of selenomolybdates with three architectures have been isolated through rational and deliberate synthetic routes by stereospecific addition of different carboxylic acids. Such an approach is potentially interesting for {SeMo6} cluster, which exhibits a high surface nucleophilicity and is capable of being functionalized by covalently bound carboxylic acids. Investigation of the assemblies reveals that carboxylic acids have good flexibility and conformational freedom, representing the powerful chemical tools to control the polyanion assembly processes.
引用
收藏
页码：14034 / 14039
页数：6
相关论文
共 50 条
  • [31] Three new inorganic-organic hybrid materials based on inorganic cluster, [(PO4)M12O36]•nH2O (M = Mo, W)
    Yousefi, Mohammad
    Eshtiagh-Hosseini, Hossein
    Mirzaei, Masoud
    Salimi, Ali R.
    Nikpour, Mohsen
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2011, 50 (01): : 51 - 54
  • [32] Synthesis and catalytic property of inorganic-organic hybrid copper vanadate Cu 2 (eIM) 6 [V 4 O 12 ] in selective oxidation of sulfides
    Li J.
    Wei C.
    Hu C.
    Li, Jikun (lijk0212@163.com), 2018, Chinese Academy of Sciences (63): : 3342 - 3349
  • [33] Hydrothermal synthesis and structural characterization of a new inorganic-organic hybrid compound with photocatalytic activity based on Keggin-type polyanion and cadmium-1, 2, 4-triazolate units
    Jiao, Yan-Qing
    Qin, Chao
    Sun, Chun-Yi
    Shao, Kui-Zhan
    Liu, Peng-Jun
    Huang, Peng
    Zhou, Kun
    Su, Zhong-Min
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 20 : 273 - 276
  • [34] Synthesis, Crystal Structure and Physicochemical Proprieties of a Cytosine Selenomolybdate Based on Strandberg-Type [Se2Mo5O21]4- Polyanion
    Nagazi, Ichraf
    Haddad, Amor
    JOURNAL OF CLUSTER SCIENCE, 2014, 25 (02) : 627 - 638
  • [35] Zr6O4(OH)4 Based Metal-Organic Frameworks for the Enhanced Chemiresistive Sensing of Ethanol
    Shukla, Avinash Kumar
    Verma, Vishal
    Goriyan, Priyanka
    Rani, Alka
    Verma, Arpit
    Singh, Ajeet
    Yadav, Bal Chandra
    Baimuratova, Rose K.
    Andreeva, Anastasia V.
    Dzhardimalieva, Gulzhian I.
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2024, 34 (08) : 3457 - 3472
  • [36] Ionic liquids coated Fe3O4 based inorganic-organic hybrid materials and their application in the simultaneous determination of DNA bases
    Kaur, Balwinder
    Srivastava, Rajendra
    COLLOIDS AND SURFACES B-BIOINTERFACES, 2014, 118 : 179 - 187
  • [37] Zeolitic inorganic-organic polymer electrolytes:: A material based on poly(ethylene glycol) 600, SnCl4 and K4Fe(CN)6
    Di Noto, V
    Barreca, D
    Furlan, C
    Armelao, L
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2000, 11 (03) : 108 - 121
  • [38] A new organic-inorganic molybdenum arsenate complex based on [(CuO6)(As3O3)2Mo6O18]4- cluster as secondary building units
    Su, Fangyong
    Zhou, Baibin
    Zhao, Zhifeng
    Su, Zhanhua
    Zhu, Chuncheng
    CRYSTAL RESEARCH AND TECHNOLOGY, 2009, 44 (04) : 447 - 452
  • [39] Divanadate-based inorganic-organic hybrid compound: {[Cu(En)2]2V2O7} • 4H2O
    Wang, K.
    Li, J.
    Liang, Z. J.
    Ma, P. T.
    Zhang, D. D.
    Niu, J. Y.
    Wang, J. P.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (11) : 795 - 799
  • [40] Fabrication of carbon paste electrode containing a new inorganic-organic hybrid based on [SiW12O40]4- polyoxoanion and Nile blue and its electrocatalytic activity toward nitrite reduction
    Kakhki, Somayeh
    Shams, Esmaeil
    Barsan, Madalina M.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2013, 704 : 80 - 85
12345