Zeolitic inorganic-organic polymer electrolytes:: A material based on poly(ethylene glycol) 600, SnCl4 and K4Fe(CN)6

This report describes the synthesis of a new zeolitic inorganic-organic polymer electrolyte with the formula [FexSny(CN)(z)Cl-v(C2nH4n+2On+1)K-1] based on poly(ethylene glycol) 600, SnCl4 and K-4[Fe(CN)(6)], and is obtained via a sol-->gel transition. Mid and far Fourie than form infrared (FT-IX) studies, analytical data and X-ray Photoelectron spectroscopy (XPS) investigations allowed us to conclude that this material is a mixed inorganic-organic network in which Fr and Sn are bonded by CN bridges and tin atoms by PEG 600 bridges. Mid-infrared (MIR) FT-IR investigations demonstrated that the polyether chains assume a conformation of the TGT (T = trans, G = gauche) type. Micrographs of the compound obtained by scanning electron microscopy reveal that ifs morphology resembles a smooth gummy paste. The conductivity of the material at different temperatures was determined by impedance spectroscopy (IS). Results indicated that the material conducts ionically and that its conductivity is strongly influenced by segmental motion of the polymer network Finally, this network shows a conductivity of ca. 3.7 x 10(-5) S/cm at 25 degrees C. Copyright (C) 2000 John Wiley & Sons, Ltd.