Selective interactions of trivalent cations Fe3+ Al3+ and Cr3+ turn on fluorescence in a naphthalimide based single molecular probe

被引：40
|
作者：
Janakipriya, Subramaniyan [1 ]
Chereddy, Narendra Reddy [2 ]
Korrapati, Purnasai [3 ]
Thennarasu, Sathiah [1 ]
Mandal, Asit Baran [4 ]
机构：
[1] CSIR Cent Leather Res Inst, Organ Chem Lab, Madras 600020, Tamil Nadu, India
[2] CSIR Indian Inst Chem Technol, Crop Protect Chem Div, Hyderabad 500007, Andhra Pradesh, India
[3] CSIR Cent Leather Res Inst, Biomat Lab, Madras 600020, Tamil Nadu, India
[4] CSIR Cent Leather Res Inst, Chem Lab, Madras 600020, Tamil Nadu, India
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2016年 / 153卷
关键词：
Naphthalimide derivative; PET inhibition; Fluorescence turn-on; Trivalent cations; Live cell imaging; ALZHEIMERS-DISEASE; ALUMINUM; IONS; FLUOROPHORE; MECHANISMS; STRATEGIES; CHROMIUM; WATER;
D O I：
10.1016/j.saa.2015.08.044
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Synthesis and fluorescence turn-on behavior of a naphthalimide based probe is described. Selective interactions of trivalent cations Fe3+, Al3+ or Cr3+ with probe 1 inhibit the PET operating in the probe, and thereby, permit the detection of these trivalent cations present in aqueous samples and live cells. Failure of other trivalent cations (Eu3+, Gd3+ and Nb3+) to inhibit the PET process in 1 demonstrates the role of chelating ring size vis-a-vis ionic radius in the selective recognition of specific metal ions. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：465 / 470
页数：6
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