Solution mediated synthesis and structure of a three-dimensional zinc arsenate, [NH3(CH2)3NH2(CH2)2 NH3][Zn4(AsO4)3(HAsO4)]•H2O, with intersecting helical channels

被引：21
|
作者：
Chakrabarti, S [1 ]
Natarajan, S [1 ]
机构：
[1] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Framework Solids Lab, Bangalore 560064, Karnataka, India
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 20期
关键词：
D O I：
10.1039/b204669p
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and single crystal structure of a zinc arsenate, [NH3(CH2)(3)NH2(CH2)(2)NH3][Zn-4(AsO4)(3)(HAsO4)].H2O, I, is presented. The structure of I is built from a network of ZnO4, AsO4 and HAsO4 tetrahedral units, connected through their vertices. The connectivity gives rise to 3-, 4- and 5-membered rings, which are joined together forming a one-dimensional column. The columns are connected forming the inter-connected helical channels bound by 8-T atoms (T = Zn and As) in the bc plane.
引用
收藏
页码：3874 / 3878
页数：5
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