Solvent extraction of zinc(II) and manganese(II) with 5,10,15,20-tetraphenyl-21H,23H-porphine (TPP) through the metal exchange reaction of lead(II)-TPP

被引：0
|
作者：
Kawai, T [1 ]
Fujiyoshi, R [1 ]
Sawamura, S [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Engn, Div Quantum Energy Engn, Sapporo, Hokkaido 0608628, Japan
来源：
SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN | 2000年 / 7卷
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A radiometric investigation was carried out on the extraction of aqueous Zn(II) and Mn(II) with a hydrophobic porphyrin (5,10,15,20-tetraphenyl-21H,23H-porphine, TPP) through a metal exchange reaction of Pb(II)-TPP. The distribution ratios (D) of these metals were found to be independent of the Pb(II) concentration in the aqueous phase. Lead(II) in the aqueous phase acted as a catalyst which promoted the metal-TPP complexation.
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页码：36 / 43
页数：8
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