Solvent extraction of zinc(II) and manganese(II) with 5,10,15,20-tetraphenyl-21H,23H-porphine (TPP) through the metal exchange reaction of lead(II)-TPP

被引：0

作者：

Kawai, T ^{[1
]}

Fujiyoshi, R ^{[1
]}

Sawamura, S ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Quantum Energy Engn, Sapporo, Hokkaido 0608628, Japan

来源：

SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN | 2000年 / 7卷

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A radiometric investigation was carried out on the extraction of aqueous Zn(II) and Mn(II) with a hydrophobic porphyrin (5,10,15,20-tetraphenyl-21H,23H-porphine, TPP) through a metal exchange reaction of Pb(II)-TPP. The distribution ratios (D) of these metals were found to be independent of the Pb(II) concentration in the aqueous phase. Lead(II) in the aqueous phase acted as a catalyst which promoted the metal-TPP complexation.

引用

页码：36 / 43

页数：8

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