Synthesis and Features of Crystal Structure of Scandium Hexa(isothiocyanato)chromate(III) Complex with Nicotinic Acid

被引：1
|
作者：
Cherkasova, E. V. [1 ]
Pervukhina, N. V. [2 ]
Kuratieva, N. V. [2 ,3 ]
Cherkasova, T. G. [1 ]
机构：
[1] Kuzbass State Tech Univ, Kemerovo 650000, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[3] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 63卷 / 06期
关键词：
D O I：
10.1134/S0036023618060050
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A double complex compound with a polymeric cation of composition [Sc-2(C6H5NO2)(3)(C6H4NO2)(3)][Cr(NCS)(6)] has been synthesized by the reaction between Sc(NO3)(3), K-3[Cr(NCS)(6)], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals are hexagonal, space group P6(3)22, Z = 2; a = 12.995(2) , c = 17.864(3) , V = 2612.3(7) 3, rho(calc) = 1.559 g/cm(3).
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页码：776 / 780
页数：5
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