Analysis of non-linear ion drift in spectrometers of ion mobility increment with cylindrical drift chamber

被引：4
|
作者：
Elistratov, A. A. [1 ]
Shibkov, S. V.
Nikolaev, E. N.
机构：
[1] Inst Cryptosyst Commun & Informat, Moscow, Russia
[2] Russian Acad Sci, Inst Chem Phys Energy Problems, Moscow V71, Russia
来源：
EUROPEAN JOURNAL OF MASS SPECTROMETRY | 2006年 / 12卷 / 03期
关键词：
ion mobility; theory; FAIMS; differential ion mobility;
D O I：
10.1255/ejms.796
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
A model for the drift of ions under a non-uniform, high-frequency electric field in the drift chamber of a spectrometer of ion mobility increment is developed. For the general dependence of the ion mobility on the electric field strength and the general time-dependence of the separating voltage, we suggest a procedure for calculating of the ion peak form. The shape of the peak for the ion focusing and defocusing conditions has been obtained.
引用
收藏
页码：153 / 160
页数：8
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