A porous metal-organic framework as active catalyst for multiple C-N/C-C bond formation reactions

被引：12

作者：

Wang, Bin ^{[1
]}

Yang, Pei ^{[1
]}

Ge, Zhi-Wei ^{[1
]}

Li, Cheng-Peng ^{[1
]}

机构：

[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin 300387, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷

基金：

中国国家自然科学基金;

关键词：

Cu(II) metal-organic framework; 4-(1H-1,2,4-triazol-1-yl)benzoic acid; C-N/C-C bond formation reactions; Catalysis; COORDINATION FRAMEWORK; STRATEGY; DESIGN;

D O I：

10.1016/j.inoche.2015.08.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D porous metal-organic framework {[Cu(4-tba)(2)](solvent)}(n) (1.S) is assembled via 4-(1H-1,2,4-triazol-1-yl)benzoic acid (Htba) and Cu(II) nodes, which shows the [2 + 2] rota-translational interpenetrating network. Interestingly, 1 displays high CO2 adsorption selectivity over CH4/H-2/O-2/Ar/N-2 gases, and acts an efficient catalyst precursor in some C-N/C-C bond formation reactions, including Chan-Lam coupling reaction of phenylboronic acid with imidazole, Suzuki-Miyoura coupling reaction of phenylboronic acids with aryl halides, and Heck coupling reaction of styrene with aryl halides. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：13 / 15

页数：3

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