A porous metal-organic framework as active catalyst for multiple C-N/C-C bond formation reactions

被引：12
|
作者：
Wang, Bin [1 ]
Yang, Pei [1 ]
Ge, Zhi-Wei [1 ]
Li, Cheng-Peng [1 ]
机构：
[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin 300387, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷
基金：
中国国家自然科学基金;
关键词：
Cu(II) metal-organic framework; 4-(1H-1,2,4-triazol-1-yl)benzoic acid; C-N/C-C bond formation reactions; Catalysis; COORDINATION FRAMEWORK; STRATEGY; DESIGN;
D O I：
10.1016/j.inoche.2015.08.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3D porous metal-organic framework {[Cu(4-tba)(2)](solvent)}(n) (1.S) is assembled via 4-(1H-1,2,4-triazol-1-yl)benzoic acid (Htba) and Cu(II) nodes, which shows the [2 + 2] rota-translational interpenetrating network. Interestingly, 1 displays high CO2 adsorption selectivity over CH4/H-2/O-2/Ar/N-2 gases, and acts an efficient catalyst precursor in some C-N/C-C bond formation reactions, including Chan-Lam coupling reaction of phenylboronic acid with imidazole, Suzuki-Miyoura coupling reaction of phenylboronic acids with aryl halides, and Heck coupling reaction of styrene with aryl halides. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：13 / 15
页数：3
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