The hydroxylation and amidation of equilenin acetate catalyzed by chloro[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato]manganese(III)

被引：93
|
作者：
Yang, J [1 ]
Weinberg, R [1 ]
Breslow, R [1 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 07期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1039/b000463o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The aromatic steroid equilenin acetate undergoes regioselective and stereoselective hydroxylation and amidation catalyzed by a manganese porphyrin using iodosobenzene (PhIO) and N-tosyliminophenyliodinane (PhINTs) as the oxygen and nitrogen donor, respectively.
引用
收藏
页码：531 / 532
页数：2
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