5,10,15,20-TETRAKIS(P-CHLOROPHENYL)-PORPHYRIN

被引：12
|
作者：
HOKELEK, T [1 ]
ULKU, D [1 ]
GUNDUZ, N [1 ]
HAYVALI, M [1 ]
KILIC, Z [1 ]
机构：
[1] UNIV ANKARA,DEPT CHEM,ANKARA,TURKEY
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270193000782
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title molecule, 2,7,12,17-tetrakis(4-chloro-phenyl)-21,22,23,24-tetraazapentacyclo[I 6.2. 1.1(3,6.-1(8,11.)1(13,16]tetracosa-1,3(22),4,6,8,10,12,14,16(4),17,-19-undecaene, is crystallographically centrosymmetric and the dihedral angle between the two pyrrole ring planes is 5.0 (4)-degrees . The molecular structure is a consequence of steric hinderances between the a-H atoms of the pyrrole and the ortho-H atoms of the phenyl rings. The dihedral angles between the pyrrole and phenyl rings are 54.8 (4) and 111. 1 (3)-degrees, respectively. The sums of the angles around meso-C atoms are -360-degrees and the average bond length between meso and adjacent macrocyclic ring C atoms is 1.398 (6) angstrom.
引用
收藏
页码：1667 / 1670
页数：4
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