Synthesis and properties of π-extended TTF analogues and their cation radical and dication salts
被引:6
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作者:
Yamashita, Y
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机构:Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
Yamashita, Y
Tomura, M
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机构:Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
Tomura, M
Uruichi, M
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机构:Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
Uruichi, M
Yakushi, K
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机构:Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
Yakushi, K
机构:
[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源:
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
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2002年
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376卷
关键词:
TTF;
electron donor;
cation radical salts;
extended conjugation;
crystal structure;
D O I:
10.1080/10587250210758
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
New bis(1,3-dithiole) electron donors containing a cyclohexene unit were prepared using a Wittig-Honer reaction and a cycloreversion reaction. The tetramethyl derivative afforded the highly conductive cation radical salts as single crystals whose unusual crystal structures were revealed by X-ray analysis.