Synthesis and properties of π-extended TTF analogues and their cation radical and dication salts

被引:6
|
作者
Yamashita, Y
Tomura, M
Uruichi, M
Yakushi, K
机构
[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 376卷
关键词
TTF; electron donor; cation radical salts; extended conjugation; crystal structure;
D O I
10.1080/10587250210758
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New bis(1,3-dithiole) electron donors containing a cyclohexene unit were prepared using a Wittig-Honer reaction and a cycloreversion reaction. The tetramethyl derivative afforded the highly conductive cation radical salts as single crystals whose unusual crystal structures were revealed by X-ray analysis.
引用
收藏
页码:19 / 24
页数:6
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