Synthesis of neutral tri- and tetranuclear organometallic clusters of group VIII transition metals

被引：2
|
作者：
Kudinov, AR
Muratov, DV
Rybinskaya, MI
Petrovskii, PV
机构：
[1] A. N. Nesmeyanov Inst. O., Russian Academy of Sciences, 117813 Moscow
来源：
RUSSIAN CHEMICAL BULLETIN | 1997年 / 46卷 / 03期
关键词：
clusters; binuclear complexes; addition; coordinatively unsaturated species;
D O I：
10.1007/BF02495415
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A number of earlier unknown tri- and tetranuclear organometallic clusters of group VIII transition metals was synthesized by the addition of coordinatively unsaturated species to a single metal-metal bond. A number of novel heteronuclear clusters, CpCp2'RhM2(mu-Co)(3)(mu(3)-CO), (Cp' = Cp, Cp*; M-2 = Ru-2, Fe-2, RuFe); Cp2Cp*Rh2M2(mu(3)-CO)(3) (M = Ru, Fe); Cp3Cp*Rh3M(mu(3)-CO)(2)(mu(3)-rl) (M = Ru, Fe); Cp2Cp*2Rh2Co2(mu(3)-CO)(2), etc., was obtained.
引用
收藏
页码：559 / 567
页数：9
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