Facile synthesis of C2-symmetric chiral binaphthyl ketone catalysts

被引：26
|
作者：
Seki, M [1 ]
Furutani, T [1 ]
Hatsuda, M [1 ]
Imashiro, R [1 ]
机构：
[1] Tanabe Seiyaku Co Ltd, Prod & Technol Dev Lab, Yodogawa Ku, Osaka 5328505, Japan
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 13期
关键词：
epoxidation; Ullmann reactions; biaryls; enzymes and enzyme reactions;
D O I：
10.1016/S0040-4039(00)00120-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
C-2-Symmetric chiral binaphthyl ketones, efficient catalysts for asymmetric epoxidation, have been synthesized through an intramolecuar Ullmann reaction and/or a lipase-catalyzed enantioselective hydrolysis of the 11-membered cyclic binaphthyl acetate. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2149 / 2152
页数：4
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