Facile synthesis of C2-symmetric chiral binaphthyl ketone catalysts

被引：26

作者：

Seki, M ^{[1
]}

Furutani, T ^{[1
]}

Hatsuda, M ^{[1
]}

Imashiro, R ^{[1
]}

机构：

[1] Tanabe Seiyaku Co Ltd, Prod & Technol Dev Lab, Yodogawa Ku, Osaka 5328505, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 13期

关键词：

epoxidation; Ullmann reactions; biaryls; enzymes and enzyme reactions;

D O I：

10.1016/S0040-4039(00)00120-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

C-2-Symmetric chiral binaphthyl ketones, efficient catalysts for asymmetric epoxidation, have been synthesized through an intramolecuar Ullmann reaction and/or a lipase-catalyzed enantioselective hydrolysis of the 11-membered cyclic binaphthyl acetate. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2149 / 2152

页数：4

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