Metal-free oxidative carbonylation on enaminone C=C bond for the cascade synthesis of benzothiazole-containing vicinal diketones

被引：73
|
作者：
Wan, Jie-Ping [1 ]
Zhou, Youyi [1 ]
Liu, Yunyun [1 ]
Sheng, Shouri [1 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China
来源：
GREEN CHEMISTRY | 2016年 / 18卷 / 02期
关键词：
WACKER-TYPE OXIDATION; MULTICOMPONENT SYNTHESIS; 1,2-ACYL MIGRATION; DOMINO REACTIONS; ALPHA-DIKETONES; KETONES; ALKYNES; CLEAVAGE; ACID; DERIVATIVES;
D O I：
10.1039/c5gc01821h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The cascade reactions between enaminones and o-aminothiophenols have been implemented to provide unprecedented vicinal diketones containing benzothiazole structures. The construction of the products has been realized under metal-free conditions via carbonylation on the C=C double bond of the enaminone. The tunable synthesis of 2-aroylbenzothiazoles has been achieved by using identical starting materials under modified reaction conditions.
引用
收藏
页码：402 / 405
页数：4
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