Metal-Free Oxidative Carbon-Heteroatom Bond Formation Through C-H Bond Functionalization

被引：239

作者：

Samanta, Rajarshi ^{[1
]}

Matcha, Kiran ^{[1
]}

Antonchick, Andrey P. ^{[1
]}

机构：

[1] Max Planck Inst Mol Physiol, Abt Chem Biol, D-44227 Dortmund, Germany

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 2013卷 / 26期

关键词：

Metal-free reactions; Green chemistry; Reaction mechanisms; Heterocycles; C-H functionalization; Hypervalent iodine; ONE-POT SYNTHESIS; HYPERVALENT IODINE(III) REAGENT; TRANSITION-METAL; HIGHLY EFFICIENT; INTERMOLECULAR AMINATION; N-ACYLAMINOPHTHALIMIDES; RADICAL AZIDONATION; CATALYZED SYNTHESIS; C(SP(3))-H BONDS; PRIMARY ALCOHOLS;

D O I：

10.1002/ejoc.201300286

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct methods of carbon-heteroatom bond formation through functionalization of non-reactive C-H bonds represent an attractive approach to the synthesis of interesting products. This review focuses on the development of metal-free coupling methods for unactivated compounds under oxidative reaction conditions. The utility of these methods in syntheses of desired products and the mechanisms of their formation are discussed with numerous examples.

引用

页码：5769 / 5804

页数：36

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