Design and Characterization of Functionally Graded Cathode Materials For Solid Oxide Fuel Cells

被引：12

作者：

Sadykov, V. ^{[1
,2
]}

Pavlova, S. ^{[1
]}

Zarubina, V. ^{[1
,2
]}

Bobin, A. ^{[1
,2
]}

Alikina, G. ^{[1
]}

Lukashevich, A. ^{[1
]}

Muzykantov, V. ^{[1
]}

Usoltsev, V. ^{[1
]}

Kharlamova, T. ^{[1
]}

Boronin, A. ^{[1
,2
]}

Koscheev, S. ^{[1
]}

Krieger, T. ^{[1
]}

Ishchenko, A. ^{[1
]}

Mezentseva, N. ^{[1
]}

Salanov, A. ^{[1
]}

Smirnova, A. ^{[3
]}

Bobrenok, O. ^{[5
]}

Uvarov, N. ^{[4
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

[3] Univ Connecticut, Dept Chem, Connecticut Global Fuel Cell Ctr, Mat & Biomol Engn, Storrs, CT 06269 USA

[4] Inst Solid State Chem & Mech Activat SB RAS Novos, Novosibirsk 630058, Russia

[5] Inst Thermophys SB RAS, Novosibirsk 630090, Russia

来源：

SOLID OXIDE FUEL CELLS 11 (SOFC-XI) | 2009年 / 25卷 / 02期

关键词：

D O I：

10.1149/1.3205794

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This work presents results on synthesis and characterization of mixed ionic-electronic conducting nanocomposite cathode materials for Intermediate Temperature Solid Oxide Fuel Cells. The corresponding materials are comprised of La0.8Sr0.2MnO3 (LSM) or La0.8Sr0.2Fe1-xNixO3-delta (x= 0.1-0.4) (LSFNx) perovskites and Sc0.1Ce0.01Zr0.89O2-x (ScCeSZ) or Ce0.9Gd0.1O2-delta (GDC) fluorites mixed via powerful ultrasonic dispersion of powders in isopropanol. Genesis of their structural properties was studied in detail by transmission electron microscopy with elemental analysis and X-ray diffraction; surface features were characterized by X-ray Photoelectron Spectroscopy. Perovskite-fluorite nanodomain interfaces appear to provide a path for fast oxygen diffusion as revealed by the oxygen isotope exchange and temperature-programmed desorption. Testing in wet H-2/air for button-size fuel cells with thin Y-doped zirconia layer and nanocomposite functionally graded cathodes demonstrated promising and stable performance in some combinations in the intermediate temperature range.

引用

页码：2403 / 2412

页数：10

共 50 条

[31] Thermal stress and probability of failure analyses of functionally graded solid oxide fuel cells
Anandakumar, Ganesh
Li, Na
Verma, Atul
Singh, Prabhakar
Kim, Jeong-Ho
JOURNAL OF POWER SOURCES, 2010, 195 (19) : 6659 - 6670
[32] Research progress of composite cathode materials for Solid oxide fuel cells
Long, Qunyang
Sha, Rui
Wang, Ruohang
Xu, Bo
Men, Haichao
Wang, Qi
Hou, Jie
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2023, 33 (03) : 267 - 278
[33] Research progress of composite cathode materials for Solid oxide fuel cells
Qunyang Long
Rui Sha
Ruohang Wang
Bo Xu
Haichao Men
Qi Wang
Jie Hou
ProgressinNaturalScience:MaterialsInternational, 2023, 33 (03) : 267 - 278
[34] OPTIMIZING OXYGEN DIFFUSION IN CATHODE MATERIALS FOR SOLID OXIDE FUEL CELLS
Chroneos, A.
Parfitt, D.
Vovk, R. V.
Goulatis, I. L.
MODERN PHYSICS LETTERS B, 2012, 26 (30):
[35] Characteristics of cathode materials for solid oxide fuel cells with mixed conductivity
Kuterbekov, K. A.
Bekmyrza, K. Zh
Nikonov, A. V.
Aydarbekov, N. K.
OPEN SCHOOL-CONFERENCE OF NIS COUNTRIES ULTRAFINE GRAINED AND NANOSTRUCTURED MATERIALS, 2018, 447
[36] Cathode materials for intermediate temperature solid oxide fuel cells.
Anderson, HU
Zhou, XD
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U562 - U562
[37] Nanocomposite Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells
Kharlamova, T.
Pavlova, S.
Sadykov, V.
Bespalko, Y.
Krieger, T.
Pelipenko, V.
Belyaev, V.
Muzykantov, V.
Alikina, G.
Okhlupin, Y.
Uvarov, N.
Smirnova, A.
SOLID OXIDE FUEL CELLS 12 (SOFC XII), 2011, 35 (01): : 2331 - 2340
[38] Design and characterization of LSM/ScCeSZ nanocomposite as mixed ionic-electronic conducting material for functionally graded cathodes of solid oxide fuel cells
Sadykov, V.
Alikina, G.
Lukashevich, A.
Muzykantov, V.
Usoltsev, V.
Boronin, A.
Koscheev, S.
Krieger, T.
Ishchenko, A.
Smirnova, A.
Bobrenok, O.
Uvarov, N.
SOLID STATE IONICS, 2011, 192 (01) : 540 - 546
[39] Cathode Polarization Degradation Characterization Experiment for Solid Oxide Fuel Cells
Park E.
Transactions of the Korean Institute of Electrical Engineers, 2023, 72 (12): : 1663 - 1669
[40] Characterization of Sr-doped neodymium cobalt oxide cathode materials for intermediate temperature solid oxide fuel cells
Lee, KT
Manthiram, A
DEVELOPMENTS IN SOLID OXIDE FUEL CELLS AND LITHIUM ION BATTERIES, 2005, 161 : 3 - 12

← 1 2 3 4 5 →