Design and Characterization of Functionally Graded Cathode Materials For Solid Oxide Fuel Cells

被引：12

作者：

Sadykov, V. ^{[1
,2
]}

Pavlova, S. ^{[1
]}

Zarubina, V. ^{[1
,2
]}

Bobin, A. ^{[1
,2
]}

Alikina, G. ^{[1
]}

Lukashevich, A. ^{[1
]}

Muzykantov, V. ^{[1
]}

Usoltsev, V. ^{[1
]}

Kharlamova, T. ^{[1
]}

Boronin, A. ^{[1
,2
]}

Koscheev, S. ^{[1
]}

Krieger, T. ^{[1
]}

Ishchenko, A. ^{[1
]}

Mezentseva, N. ^{[1
]}

Salanov, A. ^{[1
]}

Smirnova, A. ^{[3
]}

Bobrenok, O. ^{[5
]}

Uvarov, N. ^{[4
]}

机构：

[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

[3] Univ Connecticut, Dept Chem, Connecticut Global Fuel Cell Ctr, Mat & Biomol Engn, Storrs, CT 06269 USA

[4] Inst Solid State Chem & Mech Activat SB RAS Novos, Novosibirsk 630058, Russia

[5] Inst Thermophys SB RAS, Novosibirsk 630090, Russia

来源：

SOLID OXIDE FUEL CELLS 11 (SOFC-XI) | 2009年 / 25卷 / 02期

关键词：

D O I：

10.1149/1.3205794

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This work presents results on synthesis and characterization of mixed ionic-electronic conducting nanocomposite cathode materials for Intermediate Temperature Solid Oxide Fuel Cells. The corresponding materials are comprised of La0.8Sr0.2MnO3 (LSM) or La0.8Sr0.2Fe1-xNixO3-delta (x= 0.1-0.4) (LSFNx) perovskites and Sc0.1Ce0.01Zr0.89O2-x (ScCeSZ) or Ce0.9Gd0.1O2-delta (GDC) fluorites mixed via powerful ultrasonic dispersion of powders in isopropanol. Genesis of their structural properties was studied in detail by transmission electron microscopy with elemental analysis and X-ray diffraction; surface features were characterized by X-ray Photoelectron Spectroscopy. Perovskite-fluorite nanodomain interfaces appear to provide a path for fast oxygen diffusion as revealed by the oxygen isotope exchange and temperature-programmed desorption. Testing in wet H-2/air for button-size fuel cells with thin Y-doped zirconia layer and nanocomposite functionally graded cathodes demonstrated promising and stable performance in some combinations in the intermediate temperature range.

引用

页码：2403 / 2412

页数：10

共 50 条

[21] Cathode materials for intermediate temperature solid oxide fuel cells
Bhoga, S. S.
Khandale, A. P.
INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2013, 51 (05) : 305 - 309
[22] Selection of cathode contact materials for solid oxide fuel cells
Tucker, Michael C.
Cheng, Lei
DeJonghe, Lutgard C.
JOURNAL OF POWER SOURCES, 2011, 196 (20) : 8313 - 8322
[23] Review on MIEC Cathode Materials for Solid Oxide Fuel Cells
Burnwal, Suman Kumar
Bharadwaj, S.
Kistaiah, P.
JOURNAL OF MOLECULAR AND ENGINEERING MATERIALS, 2016, 4 (02)
[24] Research Progress of Cathode Materials for Solid Oxide Fuel Cells
Chang C.
Li B.
Ji B.
Men H.
Wang Q.
Xiyou Jinshu/Chinese Journal of Rare Metals, 2023, 47 (08): : 1143 - 1162
[25] Nanostructured and functionally graded cathodes for intermediate temperature solid oxide fuel cells
Liu, Y
Compson, C
Liu, ML
JOURNAL OF POWER SOURCES, 2004, 138 (1-2) : 194 - 198
[26] DUAL PORE CATHODE MATERIALS FOR SOLID OXIDE FUEL CELLS
Mosialek, M.
Zimowska, M.
Kharitonov, D.
Gorski, M.
Krzan, M.
Komenda, A.
ARCHIVES OF METALLURGY AND MATERIALS, 2020, 65 (03) : 1217 - 1221
[27] A review of sulfur poisoning of solid oxide fuel cell cathode materials for solid oxide fuel cells
Wang, Fangfang
Kishimoto, Haruo
Ishiyama, Tomohiro
Develos-Bagarinao, Katherine
Yamaji, Katsuhiko
Horita, Teruhisa
Yokokawa, Harumi
JOURNAL OF POWER SOURCES, 2020, 478
[28] Design and optimization of functionally graded anode electrode with integrated functional layer for microtubular solid oxide fuel cells
Timurkutluk, Cigdem
Altan, Tolga
Onbilgin, Sezer
Timurkutluk, Bora
CERAMICS INTERNATIONAL, 2024, 50 (20) : 38118 - 38127
[29] Characterization of tantalum doped lanthanum strontium ferrite as cathode materials for solid oxide fuel cells
Sora, Isabella Natali
Felice, Valeria
Zurlo, Francesca
Licoccia, Silvia
Di Bartolomeo, Elisabetta
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 648 : 154 - 159
[30] Functionally Graded Layers Prepared by Atmospheric Plasma Spraying for Solid Oxide Fuel Cells
Xia, W. S.
Zhang, H. O.
Wang, G. L.
Yang, Y. Z.
ADVANCED ENGINEERING MATERIALS, 2009, 11 (1-2) : 111 - 116

← 1 2 3 4 5 →