Palladium activity in 3-thiolene-1,1-dioxide hydrogenation in the presence of alkalis

被引：3
|
作者：
Mashkina, AV
Yakovleva, VN
Voskresenskaya, TP
机构：
[1] Boreskov Institute of Catalysis
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 60卷 / 01期
关键词：
hydrogenation; palladium; 3-thiolene-1,1-dioxide;
D O I：
10.1007/BF02477704
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metallic palladium supported on gamma-Al2O3 exhibits low activity in 3-thiotene-1,1-dioxide hydrogenation in alkaline alcohol solutions. It converts the above thiolene to 3-alkoxy-thiolane-1,1-dioxide, which is hydrogenated to thiolane-1,1-dioxide, at elevated temperatures favoring Pd sulfurization to PdS.
引用
收藏
页码：157 / 162
页数：6
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