Palladium activity in 3-thiolene-1,1-dioxide hydrogenation in the presence of alkalis

被引：3
|
作者：
Mashkina, AV
Yakovleva, VN
Voskresenskaya, TP
机构：
[1] Boreskov Institute of Catalysis
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 60卷 / 01期
关键词：
hydrogenation; palladium; 3-thiolene-1,1-dioxide;
D O I：
10.1007/BF02477704
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metallic palladium supported on gamma-Al2O3 exhibits low activity in 3-thiotene-1,1-dioxide hydrogenation in alkaline alcohol solutions. It converts the above thiolene to 3-alkoxy-thiolane-1,1-dioxide, which is hydrogenated to thiolane-1,1-dioxide, at elevated temperatures favoring Pd sulfurization to PdS.
引用
收藏
页码：157 / 162
页数：6
相关论文
共 50 条
  • [31] Dinitrosulfodienes of thiolene 1,1-dioxide series in electron-transfer reactions
    Efremova, IE
    Bortnikov, SV
    Berestovitskaya, VM
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2003, (08): : 1267 - 1268
  • [32] Crystal and molecular structure of 4-nitro-2-oximino-3-phenylamino-3-thiolene-1,1-dioxide
    Chekhlov, AN
    JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 44 (03) : 516 - 520
  • [33] Synthesis and Structure of 3-Methyl-2,2,4-trinitro-3-thiolene 1,1-dioxide
    V. M. Berestovitskaya
    I. E. Efremova
    A. V. Belyakov
    V. A. Tafeenko
    A. M. Abakumov
    V. V. Chernyshev
    Russian Journal of General Chemistry, 2003, 73 : 434 - 439
  • [34] New methods of the synthesis of 3-methyl-2,2,4-trinitro-3-thiolene-1,1-dioxide
    Khlytin, AL
    Efremova, IE
    Berestovitskaya, VM
    Lapshina, LV
    Gamazin, DA
    ZHURNAL ORGANICHESKOI KHIMII, 1997, 33 (10): : 1596 - 1597
  • [35] Crystal and Molecular Structure of 4-Nitro-2-oximino-3-phenylamino-3-thiolene-1,1-dioxide
    A. N. Chekhlov
    Journal of Structural Chemistry, 2003, 44 : 516 - 520
  • [36] Synthesis and structure of 3-methyl-2,2,4-trinitro-3-thiolene 1,1-dioxide
    Berestovitskaya, VM
    Efremova, IE
    Belyakov, AV
    Tafeenko, VA
    Abakumov, AM
    Chernyshev, VV
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2003, 73 (03) : 434 - 439
  • [37] SYNTHESIS AND SOME PROPERTIES OF 4-CARBOXYMETHYL-2-THIOLENE-1,1-DIOXIDE AMIDES
    SUKHOVEYEV, VV
    LUKASHOV, SM
    SLUTSKII, VI
    BEZMENOVA, TE
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1984, (12): : 1622 - 1625
  • [38] CRYSTAL AND MOLECULAR-STRUCTURE OF 4-PHENYLAMINO-2-THIOLENE-1,1-DIOXIDE
    RODE, GG
    YUFIT, DS
    BEZMENOVA, TE
    KLIMUSHEVA, GV
    UKRAINSKII KHIMICHESKII ZHURNAL, 1987, 53 (07): : 751 - 754
  • [39] CRYSTAL AND MOLECULAR-STRUCTURE OF 4-PHENYL-2-THIOLENE-1,1-DIOXIDE
    RODE, GG
    BEZMENOVA, TE
    ANTIPIN, MY
    STRUCHKOV, YT
    LITVINOV, IA
    YANOVSKII, AI
    KLIMUSHEVA, GV
    JOURNAL OF STRUCTURAL CHEMISTRY, 1984, 25 (04) : 665 - 666
  • [40] Reactions of 3-methyl-2,2,4-trinitro-3-thiolene-1,1-dioxide with pyridine and its analogies
    Berestovitskaya, VM
    Efremova, IE
    Khlytin, AL
    Berkova, GA
    Pozdnyakov, VP
    Gamazin, DA
    ZHURNAL ORGANICHESKOI KHIMII, 1996, 32 (01): : 152 - 153
12345