Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate 2∞[Be8B16O40F2] Layer lntrabridged by [B12O24] Groups

被引：19
|
作者：
Luo, Siyang [1 ,2 ]
Yao, Wenjiao [1 ,2 ,3 ]
Gong, Pifu [1 ,2 ,3 ]
Yao, Jiyong [1 ,2 ]
Lin, Zheshuai [1 ,2 ]
Chen, Chuangtian [1 ,2 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing Ctr Crystal Res & Dev, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
INORGANIC CHEMISTRY | 2014年 / 53卷 / 16期
基金：
中国国家自然科学基金;
关键词：
NONLINEAR-OPTICAL CRYSTAL; DESIGN; RB;
D O I：
10.1021/ic501444t
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel beryllium borate, Ca3Na4LiBe4B10O24F, has been discovered. It possesses a unique (2)(infinity)[Be8B16O4F2] layer composed of two opposite parallel [Be4B4O12F]infinity layers bridged with [B12O24] polyborates. The linkage of [B12O24] to other structural units is first found in anhydrous borates. In the (2)(infinity)[Be8B16O40F2] layer, multiple tunnels are arranged along different directions resided by the alkali and alkaline-earth cations. The compound remains stable in an ambient atmosphere from room temperature to the melting point at 830 degrees C and melts incongruently.
引用
收藏
页码：8197 / 8199
页数：3
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