Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate 2∞[Be8B16O40F2] Layer lntrabridged by [B12O24] Groups

被引：19
|
作者：
Luo, Siyang [1 ,2 ]
Yao, Wenjiao [1 ,2 ,3 ]
Gong, Pifu [1 ,2 ,3 ]
Yao, Jiyong [1 ,2 ]
Lin, Zheshuai [1 ,2 ]
Chen, Chuangtian [1 ,2 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing Ctr Crystal Res & Dev, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
INORGANIC CHEMISTRY | 2014年 / 53卷 / 16期
基金：
中国国家自然科学基金;
关键词：
NONLINEAR-OPTICAL CRYSTAL; DESIGN; RB;
D O I：
10.1021/ic501444t
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel beryllium borate, Ca3Na4LiBe4B10O24F, has been discovered. It possesses a unique (2)(infinity)[Be8B16O4F2] layer composed of two opposite parallel [Be4B4O12F]infinity layers bridged with [B12O24] polyborates. The linkage of [B12O24] to other structural units is first found in anhydrous borates. In the (2)(infinity)[Be8B16O40F2] layer, multiple tunnels are arranged along different directions resided by the alkali and alkaline-earth cations. The compound remains stable in an ambient atmosphere from room temperature to the melting point at 830 degrees C and melts incongruently.
引用
收藏
页码：8197 / 8199
页数：3
相关论文
共 50 条
  • [21] Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10
    Wang, Yongjiang
    Pan, Shilie
    Hou, Xueling
    Liu, Gang
    Wang, Jide
    Jia, Dianzeng
    SOLID STATE SCIENCES, 2010, 12 (10) : 1726 - 1730
  • [22] Sn2B7O12F with a 2 1[ B14O24] 6-layer constructed from the unprecedented [ B7O16] 11-fundamental building block
    Lu, Zixiu
    Zhang, Fangfang
    Tudi, Abudukadi
    Zhang, Zhizhong
    Yang, Zhihua
    Pan, Shilie
    INORGANIC CHEMISTRY FRONTIERS, 2019, 6 (04) : 996 - 1002
  • [23] Preparation and Characterization of novel borate K2O•CaO•4B2O3•12H2O:Sm3+
    Bi, Ying
    Tian, Yan-wen
    Wang, Guo-sheng
    Cao, Fa-bin
    Xia, Lin-jiu
    CHEMICAL ENGINEERING AND MATERIAL PROPERTIES, PTS 1 AND 2, 2012, 391-392 : 1027 - +
  • [24] The new high-pressure borate Co7B24O42(OH)2•2 H2O-Formation of edge-sharing BO4 tetrahedra in a hydrated borate
    Neumair, Stephanie C.
    Kaindl, Reinhard
    Huppertz, Hubert
    JOURNAL OF SOLID STATE CHEMISTRY, 2012, 185 : 1 - 9
  • [25] Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18]6- network and isolated [B2O5]4- unit
    Zhang, Min
    Pan, Shilie
    Han, Jian
    Yang, Zhihua
    Su, Xin
    Zhao, Wenwu
    JOURNAL OF SOLID STATE CHEMISTRY, 2012, 190 : 92 - 97
  • [26] The first praseodymium fluoride borate Pr4B3O10F - High-pressure synthesis and characterization
    Haberer, Almut
    Kaindl, Reinhard
    Huppertz, Hubert
    SOLID STATE SCIENCES, 2010, 12 (04) : 515 - 521
  • [27] Introduction of the [B-O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F2
    Cheng, Bingliang
    Ma, Wenjuan
    Tudi, Abudukadi
    Liu, Changyou
    Long, Xifa
    Yang, Yun
    INORGANIC CHEMISTRY, 2023, 62 (31) : 12187 - 12191
  • [28] Preparation and Structure of the Non-centrosymmetric Hydrated Borate: K2Ca[B4O5(OH)4]2•8H2O
    Bi, Ying
    Tian, Yan-Wen
    Wang, Guo-Sheng
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (13) : 7346 - 7350
  • [29] Gd4B4O11F2: Synthesis and crystal structure of a rare-earth fluoride borate exhibiting a new "fundamental building block" in borate chemistry
    Haberer, Almut
    Kaindl, Reinhard
    Huppertz, Hubert
    JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (02) : 471 - 478
  • [30] A New Sodium Borate: Na[B6O8(OH)3]•6H2O•H3BO3
    Kose, Dursun Ali
    Zumreoglu-Karan, Birguel
    Hokelek, Tuncer
    Sahin, Ertan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (03): : 563 - 566
12345