Selective functional transformation of 1,2-diols via organophosphorus reagents

被引：0

作者：

Pirat, JL ^{[1
]}

Carteron, M ^{[1
]}

Maggio, AF ^{[1
]}

Bot, S ^{[1
]}

Cristau, HJ ^{[1
]}

机构：

[1] Ecole Natl Super Chim Montpellier, Chim Organ Lab, CNRS, ESA 5076, F-34296 Montpellier 5, France

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1999年 / 144卷

关键词：

1,3,2 lambda(5)-dioxaphospholanes; 1,2-diols; electrophilic activation;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new synthesis of 1,3,2 lambda(5)-dioxaphospholanes was realized by direct reaction of dibromotriphenylphosphorane with 1,2-diols. Ring opening studies were performed with or without electrophilic activation (Lewis acids or hydrogen bonding) in order to substitute selectively one of the hydroxy function.

引用

页码：609 / 612

页数：4

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