Selective functional transformation of 1,2-diols via organophosphorus reagents

被引:0
|
作者
Pirat, JL [1 ]
Carteron, M [1 ]
Maggio, AF [1 ]
Bot, S [1 ]
Cristau, HJ [1 ]
机构
[1] Ecole Natl Super Chim Montpellier, Chim Organ Lab, CNRS, ESA 5076, F-34296 Montpellier 5, France
关键词
1,3,2 lambda(5)-dioxaphospholanes; 1,2-diols; electrophilic activation;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new synthesis of 1,3,2 lambda(5)-dioxaphospholanes was realized by direct reaction of dibromotriphenylphosphorane with 1,2-diols. Ring opening studies were performed with or without electrophilic activation (Lewis acids or hydrogen bonding) in order to substitute selectively one of the hydroxy function.
引用
收藏
页码:609 / 612
页数:4
相关论文
共 50 条
  • [31] EcoMnOx, a Biosourced Catalyst for Selective Aerobic Oxidative Cleavage of Activated 1,2-Diols
    Escande, Vincent
    Lam, Chun Ho
    Grison, Claude
    Anastas, Paul T.
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (04): : 3214 - 3222
  • [32] Selective sulfonylation of 1,2-diols and derivatives catalyzed by a recoverable fluorous tin oxide
    Bucher, B
    Curran, DP
    TETRAHEDRON LETTERS, 2000, 41 (49) : 9617 - 9621
  • [33] Self-association of 1,2-diols - Apparent heat capacities of 1,2-diols in n-heptane and carbon tetrachloride
    Salcedo, D
    Costas, M
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (21): : 3781 - 3789
  • [34] Microbial Oxidation of 1,2-Diols Bearing a Substituent with an Oxyfunctional Group: Preparation of Optically Active 1,2-Diols and α-Hydroxy Ketones
    Matsumoto, Kazutsugu
    Hashimoto, Key
    Sakuragi, Mari
    Kusunoki, Ayumi
    Nogawa, Masaki
    LETTERS IN ORGANIC CHEMISTRY, 2011, 8 (08) : 536 - 539
  • [35] Selective xylose hydrogenolysis to 1,2-diols using Co@NC catalysts
    Liang Y.
    Li Z.-J.
    Liu Q.-Y.
    Ma L.-L.
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2021, 49 (12): : 1898 - 1910
  • [36] STEREOCHEMICAL EQUILIBRATION OF THE LITHIUM DERIVATIVES OF 1,2-DIOLS
    SLEMON, CE
    YATES, P
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (03): : 304 - 313
  • [37] PROTECTION OF 1,2-DIOLS AS CYCLIC ORTHO ESTERS
    LAMM, B
    FRANTSI, M
    ACTA PHARMACEUTICA SUECICA, 1986, 23 (06): : 410 - 411
  • [38] LONG-CHAIN 1,2-DIOLS AND THEIR PREPARATION
    RUTZEN, H
    FETTE SEIFEN ANSTRICHMITTEL, 1979, 81 (12): : 477 - 477
  • [39] A MILD PROCEDURE FOR THE CONVERSION OF 1,2-DIOLS TO OLEFINS
    COREY, EJ
    HOPKINS, PB
    TETRAHEDRON LETTERS, 1982, 23 (19) : 1979 - 1982
  • [40] CHROMIC ACID OXIDATION OF DIASTEREOISOMERIC 1,2-DIOLS
    HEINDEL, ND
    HANRAHAN, ES
    SINKOVIT.RJ
    JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (06): : 2019 - &