Selective functional transformation of 1,2-diols via organophosphorus reagents

被引：0
|
作者：
Pirat, JL [1 ]
Carteron, M [1 ]
Maggio, AF [1 ]
Bot, S [1 ]
Cristau, HJ [1 ]
机构：
[1] Ecole Natl Super Chim Montpellier, Chim Organ Lab, CNRS, ESA 5076, F-34296 Montpellier 5, France
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1999年 / 144卷
关键词：
1,3,2 lambda(5)-dioxaphospholanes; 1,2-diols; electrophilic activation;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new synthesis of 1,3,2 lambda(5)-dioxaphospholanes was realized by direct reaction of dibromotriphenylphosphorane with 1,2-diols. Ring opening studies were performed with or without electrophilic activation (Lewis acids or hydrogen bonding) in order to substitute selectively one of the hydroxy function.
引用
收藏
页码：609 / 612
页数：4
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