Molybdenum(V) and molybdenum(IV) coordination compounds from the reactions of MoCl5 with sulfones

被引：4
|
作者：
Ferretti, Eleonora [1 ]
Hayatifar, Mohammad [1 ]
Marchetti, Fabio [1 ]
Pampaloni, Guido [1 ]
Zacchini, Stefano [2 ]
机构：
[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56124 Pisa, Italy
[2] Univ Bologna, Dipartimento Chim Ind Toso Montanari, I-40136 Bologna, Italy
来源：
POLYHEDRON | 2015年 / 100卷
关键词：
Molybdenum pentachloride; Coordination complexes; Metal reduction; Sulfones; X-ray structure; LIVING CATIONIC-POLYMERIZATION; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; VINYL ETHER; PENTACHLORIDE; COMPLEXES; CATALYSTS; OXYGEN; ACTIVATION; CHLORIDE;
D O I：
10.1016/j.poly.2015.09.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The mononuclear complexes MoCl5L (L = 2,5-dihydrothiophene-1,1-dioxide), 1, and MoCl4L2 (L = dimethylsulfone, 2; diethylsulfone, 3; diphenylsulfone, 4) were obtained by the reactions of MoCl5 with the corresponding sulfones at room temperature in dichloromethane, and were characterized by analytical and magnetic data, and by X-ray crystallography in the cases of 1 and 2. The X-ray structure of 1 is the first one ever reported for an adduct of MoCl5 with a carbon-containing species. (C) 2015 Published by Elsevier Ltd.
引用
收藏
页码：400 / 403
页数：4
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