Molybdenum(V) and molybdenum(IV) coordination compounds from the reactions of MoCl5 with sulfones

被引：4

作者：

Ferretti, Eleonora ^{[1
]}

Hayatifar, Mohammad ^{[1
]}

Marchetti, Fabio ^{[1
]}

Pampaloni, Guido ^{[1
]}

Zacchini, Stefano ^{[2
]}

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56124 Pisa, Italy

[2] Univ Bologna, Dipartimento Chim Ind Toso Montanari, I-40136 Bologna, Italy

来源：

POLYHEDRON | 2015年 / 100卷

关键词：

Molybdenum pentachloride; Coordination complexes; Metal reduction; Sulfones; X-ray structure; LIVING CATIONIC-POLYMERIZATION; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; VINYL ETHER; PENTACHLORIDE; COMPLEXES; CATALYSTS; OXYGEN; ACTIVATION; CHLORIDE;

D O I：

10.1016/j.poly.2015.09.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mononuclear complexes MoCl5L (L = 2,5-dihydrothiophene-1,1-dioxide), 1, and MoCl4L2 (L = dimethylsulfone, 2; diethylsulfone, 3; diphenylsulfone, 4) were obtained by the reactions of MoCl5 with the corresponding sulfones at room temperature in dichloromethane, and were characterized by analytical and magnetic data, and by X-ray crystallography in the cases of 1 and 2. The X-ray structure of 1 is the first one ever reported for an adduct of MoCl5 with a carbon-containing species. (C) 2015 Published by Elsevier Ltd.

引用

页码：400 / 403

页数：4

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