Phase Equilibria in Water-Salt Systems Consisting of Potassium, Sodium, and Ammonium Carbonates and Anti-Icing Properties of Carbonate Compositions

被引：0

作者：

Frolova, E. A. ^{[1
]}

Kondakov, D. F. ^{[1
]}

Avdyushkina, L. I. ^{[2
]}

Bykov, A. V. ^{[3
]}

Shkarupin, A. N. ^{[3
]}

Danilov, V. P. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] All Russian Sci Res Inst Aviat Mat, Moscow 105005, Russia

[3] Test Lab Co Ltd, Reg Certificat Ctr, Balashikha 143913, Moscow Oblast, Russia

来源：

THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING | 2018年 / 52卷 / 04期

关键词：

water-salt systems; phase equilibria; potassium; sodium; ammonium carbonates; anti-icing compositions;

D O I：

10.1134/S0040579518040103

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Phase equilibria in K2CO3-H2O, Na2CO3-H2O, K2CO3-Na2CO3-H2O, K2CO3-(NH4)(2)CO3-H2O systems under temperatures ranging from 0 down to -36 degrees C are investigated. The carbonate compositions forming low-temperature eutectics are revealed. Their melting ability with respect to ice under temperatures -5 and -10 degrees C is determined. It was found that potassium carbonate is characterized by sufficient anti-icing properties. Potassium carbonate composition activity is determined with respect to metals. Efficient corrosion inhibiters are selected. It was found that potassium carbonate is aggressive with respect to cement concrete. Special protection is necessary, if potassium carbonate is used on cement concrete coatings.

引用

页码：587 / 590

页数：4

共 35 条

[1] Phase Equilibria in Water-Salt Systems Consisting of Potassium, Sodium, and Ammonium Carbonates and Anti-Icing Properties of Carbonate Compositions
E. A. Frolova
D. F. Kondakov
L. I. Avdyushkina
A. V. Bykov
A. N. Shkarupin
V. P. Danilov
Theoretical Foundations of Chemical Engineering, 2018, 52 : 587 - 590
[2] Phase equilibria in the sodium formate–potassium formate–water system below 0°c and the anti-icing properties of salt compositions
E. A. Frolova
D. F. Kondakov
V. V. Nikolaev
O. P. Tin’gaev
V. P. Danilov
Theoretical Foundations of Chemical Engineering, 2015, 49 : 719 - 720
[3] Phase equilibria in the sodium formate-potassium formate-water system below 0A°c and the anti-icing properties of salt compositions
Frolova, E. A.
Kondakov, D. F.
Nikolaev, V. V.
Tin'gaev, O. P.
Danilov, V. P.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2015, 49 (05) : 719 - 720
[4] Phase equilibria in water-salt systems from sodium, magnesium, and calcium nitrates and deicing properties of nitrate compositions
Frolova, E. A.
Kondakov, D. F.
Avdyushkina, L. I.
Bykov, A. V.
Shkarupin, A. N.
Danilov, V. P.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2017, 51 (04) : 523 - 526
[5] Phase Equilibria in the Sections of a Carbamide–Sodium Formate–Water System at 0 to –22°C and Anti-Icing Properties of the Salt Compounds
V. P. Danilov
E. A. Frolova
D. F. Kondakov
M. N. Brekhovskikh
Theoretical Foundations of Chemical Engineering, 2019, 53 : 612 - 614
[6] Calculation of phase equilibria in water-salt systems simulating the natural carbonate brines
Charykova, MV
GEOCHEMISTRY INTERNATIONAL, 2000, 38 : S206 - S213
[7] Phase Equilibria in Multicomponent Water-Salt Systems
Tursunbadalov, Sherali
Soliev, Lutfullo
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (07): : 2209 - 2220
[8] Phase Equilibria in the Sodium-Acetate–Sodium-Formate–Water System at Temperatures of from 0 to–22°C and the Anti-icing Properties of Compositions Based on These Salts
V. P. Danilov
E. A. Frolova
D. F. Kondakov
Theoretical Foundations of Chemical Engineering, 2018, 52 : 859 - 861
[9] Phase Equilibria in the Sodium-Acetate-Sodium-Formate-Water System at Temperatures of from 0 to-22°C and the Anti-icing Properties of Compositions Based on These Salts
Danilov, V. P.
Frolova, E. A.
Kondakov, D. F.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2018, 52 (05) : 859 - 861
[10] Investigation of Phase Equilibria in Quinary Water-Salt Systems
Tursunbadalov, Sherali
Soliev, Lutfullo
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2018, 63 (03): : 598 - 612

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