Phase Equilibria in Water-Salt Systems Consisting of Potassium, Sodium, and Ammonium Carbonates and Anti-Icing Properties of Carbonate Compositions

被引:0
|
作者
Frolova, E. A. [1 ]
Kondakov, D. F. [1 ]
Avdyushkina, L. I. [2 ]
Bykov, A. V. [3 ]
Shkarupin, A. N. [3 ]
Danilov, V. P. [1 ]
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[2] All Russian Sci Res Inst Aviat Mat, Moscow 105005, Russia
[3] Test Lab Co Ltd, Reg Certificat Ctr, Balashikha 143913, Moscow Oblast, Russia
关键词
water-salt systems; phase equilibria; potassium; sodium; ammonium carbonates; anti-icing compositions;
D O I
10.1134/S0040579518040103
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Phase equilibria in K2CO3-H2O, Na2CO3-H2O, K2CO3-Na2CO3-H2O, K2CO3-(NH4)(2)CO3-H2O systems under temperatures ranging from 0 down to -36 degrees C are investigated. The carbonate compositions forming low-temperature eutectics are revealed. Their melting ability with respect to ice under temperatures -5 and -10 degrees C is determined. It was found that potassium carbonate is characterized by sufficient anti-icing properties. Potassium carbonate composition activity is determined with respect to metals. Efficient corrosion inhibiters are selected. It was found that potassium carbonate is aggressive with respect to cement concrete. Special protection is necessary, if potassium carbonate is used on cement concrete coatings.
引用
收藏
页码:587 / 590
页数:4
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