Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

被引：64

作者：

Mercier, Audrey ^{[1
]}

Yeo, Wee Chuan ^{[1
]}

Chou, Jingyu ^{[1
]}

Chaudhuri, Piyali Datta ^{[1
]}

Bernardinelli, Gerald ^{[1
]}

Kuendig, E. Peter ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 35期

基金：

瑞士国家科学基金会;

关键词：

ANTI-MARKOVNIKOV HYDRATION; ENANTIOSELECTIVE METHOXYCARBONYLATION; BENZYLIC ALCOHOL; ARENE COMPOUNDS; INDUCTION; RESOLUTION; LIGAND; IRON;

D O I：

10.1039/b910977c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF6], the precursor of [RuCp(CH3CN)(3)][PF6], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.

引用

页码：5227 / 5229

页数：3

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