Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

被引：64
|
作者：
Mercier, Audrey [1 ]
Yeo, Wee Chuan [1 ]
Chou, Jingyu [1 ]
Chaudhuri, Piyali Datta [1 ]
Bernardinelli, Gerald [1 ]
Kuendig, E. Peter [1 ]
机构：
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 35期
基金：
瑞士国家科学基金会;
关键词：
ANTI-MARKOVNIKOV HYDRATION; ENANTIOSELECTIVE METHOXYCARBONYLATION; BENZYLIC ALCOHOL; ARENE COMPOUNDS; INDUCTION; RESOLUTION; LIGAND; IRON;
D O I：
10.1039/b910977c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF6], the precursor of [RuCp(CH3CN)(3)][PF6], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.
引用
收藏
页码：5227 / 5229
页数：3
相关论文
共 50 条
  • [21] Chiral Salicyloxazolines as Auxiliaries for the Asymmetric Synthesis of Ruthenium Polypyridyl Complexes
    Gong, Lei
    Mulcahy, Seann P.
    Devarajan, Deepa
    Harms, Klaus
    Frenking, Gernot
    Meggers, Eric
    INORGANIC CHEMISTRY, 2010, 49 (17) : 7692 - 7699
  • [22] Various P*-chiral phosphite-type ligands:: their synthesis, stereochemistry and use in Pd-catalysed allylation
    Benetsky, Eduard B.
    Zheglov, Sergey V.
    Grishina, Tatiana B.
    Macaev, Fliur Z.
    Bet, Liudmila P.
    Davankov, Vadim A.
    Gavrilov, Konstantin N.
    TETRAHEDRON LETTERS, 2007, 48 (47) : 8326 - 8330
  • [23] Highly efficient and enantioselective synthesis of chiral lactones via Ir-catalysed asymmetric hydrogenation of ketoesters
    Song, Jingyuan
    Yin, Congcong
    Zhang, Yao
    Shi, Yongjie
    Li, Yingjun
    Chen, Gen-Qiang
    Zhang, Xumu
    CHEMICAL COMMUNICATIONS, 2022, 58 (60) : 8408 - 8411
  • [24] A novel asymmetric synthesis of highly enantiomerically enriched norbornane-type diamine derivatives
    Bolm, C
    Schiffers, I
    Atodiresei, I
    Ozcubukcu, S
    Raabe, G
    NEW JOURNAL OF CHEMISTRY, 2003, 27 (01) : 14 - 17
  • [25] SYNTHESIS OF HIGHLY ENANTIOMERICALLY ENRICHED CYCLIC AMINES BY THE CATALYTIC ASYMMETRIC HYDROGENATION OF CYCLIC IMINES
    WILLOUGHBY, CA
    BUCHWALD, SL
    JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (27): : 7627 - 7629
  • [26] Synthesis of non-equivalent diamides and amido-esters via Pd-catalysed carbonylation
    Yao Ge
    Weiheng Huang
    Sebastian Ahrens
    Anke Spannenberg
    Ralf Jackstell
    Matthias Beller
    Nature Synthesis, 2024, 3 : 202 - 213
  • [27] Synthesis of 2-Substitued Indoles via Pd-Catalysed Cyclization in an Aqueous Micellar Medium
    Siciliano, Sofia
    Cini, Elena
    Taddei, Maurizio
    Vinciarelli, Giorgia
    MOLECULES, 2021, 26 (13):
  • [28] Synthesis and property of planar-chiral cyclopentadienyl-ruthenium complexes
    Komatsuzaki, N
    Uno, M
    Kikuchi, H
    Takahashi, S
    CHEMISTRY LETTERS, 1996, (08) : 677 - 678
  • [29] Synthesis of non-equivalent diamides and amido-esters via Pd-catalysed carbonylation
    Ge, Yao
    Huang, Weiheng
    Ahrens, Sebastian
    Spannenberg, Anke
    Jackstell, Ralf
    Beller, Matthias
    NATURE SYNTHESIS, 2024, 3 (02): : 175 - 184
  • [30] Synthesis of Enantiomerically Enriched Chiral Tetrahydroquinolines via Sequential Dearomatization/Enantioselective Borylation Reactions
    Kubota, Koji
    Watanabe, Yuta
    Ito, Hajime
    ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (15) : 2379 - 2384
12345