Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

被引：64
|
作者：
Mercier, Audrey [1 ]
Yeo, Wee Chuan [1 ]
Chou, Jingyu [1 ]
Chaudhuri, Piyali Datta [1 ]
Bernardinelli, Gerald [1 ]
Kuendig, E. Peter [1 ]
机构：
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 35期
基金：
瑞士国家科学基金会;
关键词：
ANTI-MARKOVNIKOV HYDRATION; ENANTIOSELECTIVE METHOXYCARBONYLATION; BENZYLIC ALCOHOL; ARENE COMPOUNDS; INDUCTION; RESOLUTION; LIGAND; IRON;
D O I：
10.1039/b910977c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF6], the precursor of [RuCp(CH3CN)(3)][PF6], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.
引用
收藏
页码：5227 / 5229
页数：3
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