One-pot lipase-catalyzed synthesis of enantiopure secondary alcohols from carbonyl compounds: a new protocol for lipase-mediated resolution

被引：48

作者：

Kamal, A ^{[1
]}

Sandbhor, M ^{[1
]}

Ramana, KV ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem, Biotransformat Lab, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(02)00170-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of acetophenones with sodium borohydride in the presence of neutral alumina in hexane followed by enantioselective acylation catalyzed by Pseudomonas cepacia lipase has been achieved in one-pot. Further, immobilized lipase offered a high degree of selectivity with spontaneity. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：815 / 820

页数：6

共 50 条

[21] Application of a one-pot lipase resolution strategy for the synthesis of chiral γ- and δ-lactones
Kamal, A
Sandbhor, M
Shaik, AA
TETRAHEDRON-ASYMMETRY, 2003, 14 (11) : 1575 - 1580
[22] Ionic Liquid Engineering for Lipase-Mediated Optical Resolution of Secondary Alcohols: Design of Ionic Liquids Applicable to Ionic Liquid Coated-Lipase Catalyzed Reaction
Abe, Yoshikazu
Yagi, Yusuke
Hayase, Shuichi
Kawatsura, Motoi
Itoh, Toshiyuki
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (30) : 9952 - 9958
[23] CAN catalyzed one-pot synthesis of α-amino phosphonates from carbonyl compounds
Ravinder, K
Reddy, AV
Krishnaiah, P
Venkataramana, G
Reddy, VLN
Venkateswarlu, Y
SYNTHETIC COMMUNICATIONS, 2004, 34 (09) : 1677 - 1683
[24] Synthesis of optically active phosphorus compounds using lipase-catalyzed optical resolution
Shioji, Kosei
Ueda, Nobuaki
Okuma, Kentaro
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2007, 48 (3-4) : 115 - 115
[25] A highly efficient chemoselective synthesis of 3,5-diketoesters by lipase-catalyzed transesterification: application to the resolution of secondary alcohols
Nanda, S
Scott, AI
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2004, 30 (01) : 1 - 12
[26] ONE-POT SYNTHESIS OF OPTICALLY-ACTIVE CYANOHYDRIN ACETATES FROM ALDEHYDES VIA LIPASE-CATALYZED KINETIC RESOLUTION COUPLED WITH INSITU FORMATION AND RACEMIZATION OF CYANOHYDRINS
INAGAKI, M
HIRATAKE, J
NISHIOKA, T
ODA, J
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (21): : 5643 - 5649
[27] Promiscuous lipase catalyzed a new P-C bond formation: Green and efficient protocol for one-pot synthesis of α-aminophosphonates
Guezane-Lakoud, Samia
Toffano, Martial
Aribi-Zouioueche, Louisa
HETEROATOM CHEMISTRY, 2017, 28 (06)
[28] One-Pot Oxidation-Hydrocyanation Sequence Coupled to Lipase-Catalyzed Diastereoresolution in the Chemoenzymatic Synthesis of Sugar Cyanohydrin Esters
Hietanen, Ari
Kanerva, Liisa T.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 2012 (14) : 2729 - 2737
[29] ENZYMES IN ORGANIC-SYNTHESIS - LIPASE-CATALYZED RESOLUTION OF SECONDARY ALPHA-KETOALCOHOLS
DUH, TH
WANG, YF
WU, MJ
TETRAHEDRON-ASYMMETRY, 1993, 4 (08) : 1793 - 1794
[30] Lipase-Catalyzed Kinetic Resolution of Alcohols as Intermediates for the Synthesis of Heart Rate Reducing Agent Ivabradine
Morandini, Anna
Rossetti, Arianna
Sacchetti, Alessandro
CATALYSTS, 2021, 11 (01) : 1 - 10

← 1 2 3 4 5 →